The reaction of hydroperoxy-propyl radicals with molecular oxygen
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چکیده
منابع مشابه
Computational Model of Reaction Mechanism of Alkyl Peroxy Radicals with Organic Compounds in the Presence and Absence of Oxygen
On the basis of experimental data a kinetic model for the heterogeneous interaction between alkylperoxyradicals and organic compounds in Langmuir- Hinshelwood approach at room temperature has been offered.The effect of oxygen on the kinetics of process in the presence, [O2]o = 1 x 1011 – 1.6 x 1012 molecules.cm-2, and absence of oxygen has been analyzed. Over time the chain degenerate branching...
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Efficient electrochemical splitting of H2O to O2 and H2 fuels has become an important goal in the quest for a renewable source of energy. A major source of the inefficiency of this process is the significant overpotential associated with the anodic oxygen evolution reaction (OER). Understanding the mechanism of the OER could help in identifying the elementary processes contributing to OER overp...
متن کاملcomputational model of reaction mechanism of alkyl peroxy radicals with organic compounds in the presence and absence of oxygen
on the basis of experimental data a kinetic model for the heterogeneous interaction between alkylperoxyradicals and organic compounds in langmuir- hinshelwood approach at room temperature has been offered.the effect of oxygen on the kinetics of process in the presence, [o2]o = 1 x 1011 – 1.6 x 1012 molecules.cm-2, and absence of oxygen has been analyzed. over time the chain degenerate branching...
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Using quantum mechanical calculations, we have investigated hydrogen shift (H-shift) reactions in peroxy radicals derived from the atmospheric oxidation of 1-pentene (CH2═CHCH2CH2CH3) and its monosubstituted derivatives. We investigate the peroxy radicals, HOCH2CH(OO)CR1HCH2CH3, HOCH2CH(OO)CH2CR1HCH3, and HOCH2CH(OO)CH2CH2CR1H2, where the substituent R1 is an alcoholic (OH), a hydroperoxy (OOH)...
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ژورنال
عنوان ژورنال: Symposium (International) on Combustion
سال: 1994
ISSN: 0082-0784
DOI: 10.1016/s0082-0784(06)80711-3